New Dye-Ligand: Procion Red MX-3B Carrying Poly(EGDMA-HEMA) Microbeads for Removal of Copper Ions

Yazarlar

A. Deni̇zli̇, E. Büyüktuncel, Z. Said, Ö. Genç, E. Pişkin

Yayın

1998

DOI

10.1080/10601329808002021

Atıflar

5

Özet

Procion Red MX-3B-attached poly(ethylene glycol dimethacrylate-hydroxy-ethyl methacrylate [poly(EGDMA-HEMA)] microbeads were prepared for removal of Cu2+ ions from aqueous media containing different amounts of Cu2+ ions (2–50 ppm). Procion Red MX-3B-attached microbeads were characterized by FTIR, optical microscopy and elemental analysis. Dye-attached microbeads with a swelling ratio of 55% and carrying 8.95 μmol Procion Red MX-3B/g polymer were used in the adsorption-desorption of Cu2+ ions. Very high adsorption rates were observed at the beginning of adsorption process and then equilibrium was achieved in about 5–10 minutes. The maximum adsorption of Cu2+ ions onto the Procion Red MX-3B-attached poly(EGDMA-HEMA) microbeads (i.e., by chelate formation of Cu2+ ions with dye molecules) was about 4.6 mg Cu2+ ions/g polymer, which was observed at pH 7.5. Adsorption onto the plain poly(EGDMA-HEMA) microbeads (i.e., nonspecific adsorption) was about 0.36 mg Cu2+ ions/g polymer under the same experimental conditions. More than 90% of the adsorbed Cu2+ ions was desorbed in 15 minutes by using 0.1 M HNO3 as an desorption agent.

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BibTeX

@article{a1998,
  title   = {New Dye-Ligand: Procion Red MX-3B Carrying Poly(EGDMA-HEMA) Microbeads for Removal of Copper Ions},
  author  = {A. Deni̇zli̇ and E. Büyüktuncel and Z. Said and Ö. Genç and E. Pişkin},
  doi     = {10.1080/10601329808002021},
  year    = {1998}
}

← Tüm yayınlar DOI: 10.1080/10601329808002021